dc.contributor.author | Mambanda, Allen | |
dc.contributor.author | Kanyora, Amos K. | |
dc.contributor.author | Ongoma, Peter | |
dc.contributor.author | Gichumbi, Joel | |
dc.contributor.author | Omondi, Reinner O. | |
dc.date.accessioned | 2022-11-03T09:15:39Z | |
dc.date.available | 2022-11-03T09:15:39Z | |
dc.date.issued | 2022 | |
dc.identifier.citation | Mambanda, A.; Kanyora, A.K.; Ongoma, P.; Gichumbi, J.; Omondi, R.O. Chlorido-(η 6 -pcymene)-(bis(pyrazol-1-yl)methaneκ 2N,N0 )Osmium(II) Tetrafluoroborate, C17H22BClF4N4Os. Molbank 2022, 2022, M1429. https://doi.org/ 10.3390/M1429 | en_US |
dc.identifier.uri | http://repository.chuka.ac.ke/handle/chuka/15495 | |
dc.description.abstract | The powder of the arene osmium(II) complex, [Os(II)(dpzm)(η
6
-p-cym)Cl]BF4
(dpzm =
di(1H-pyrazol-1-yl)methane; η
6
-p-cym = para-cymene), with a formula of C17H22BClF4N4Os (referred
to herein as 1) was isolated from the reaction of [(η
6
-p-cym)Os(µ-Cl)(Cl)]2 with dpzm dissolved in
acetonitrile and under a flow of nitrogen gas. It was characterized by spectroscopic techniques
(viz., FTIR, 1H NMR, UV-Visible absorption). Yellow crystal blocks of 1 were grown by the slow
evaporation from the methanolic solution of its powder. The single-crystal X-ray structure of 1 was
solved by diffraction analysis on a Bruker APEX Duo CCD area detector diffractometer using the
Cu(Kα), λ = 1.54178 Å as the radiation source, and 1 crystallizes in the monoclinic crystal system and
the C2/c (no. 15) space group. | en_US |
dc.language.iso | en | en_US |
dc.publisher | MDPI | en_US |
dc.relation.ispartofseries | molbank; | |
dc.subject | arene osmium(II) complex | en_US |
dc.subject | di(1H-pyrazol-1-yl)methane | en_US |
dc.subject | para-cymene | en_US |
dc.subject | piano stool geometry | en_US |
dc.subject | pseudo-octahedral geometry | en_US |
dc.title | Chlorido-(η 6 -p-cymene)-(bis(pyrazol-1-yl)methaneκ 2N,N0 )Osmium(II) Tetrafluoroborate, C17H22BClF4N4Os | en_US |
dc.type | Article | en_US |