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dc.contributor.authorMambanda, Allen
dc.contributor.authorKanyora, Amos K.
dc.contributor.authorOngoma, Peter
dc.contributor.authorGichumbi, Joel
dc.contributor.authorOmondi, Reinner O.
dc.date.accessioned2022-11-03T09:15:39Z
dc.date.available2022-11-03T09:15:39Z
dc.date.issued2022
dc.identifier.citationMambanda, A.; Kanyora, A.K.; Ongoma, P.; Gichumbi, J.; Omondi, R.O. Chlorido-(η 6 -pcymene)-(bis(pyrazol-1-yl)methaneκ 2N,N0 )Osmium(II) Tetrafluoroborate, C17H22BClF4N4Os. Molbank 2022, 2022, M1429. https://doi.org/ 10.3390/M1429en_US
dc.identifier.urihttp://repository.chuka.ac.ke/handle/chuka/15495
dc.description.abstractThe powder of the arene osmium(II) complex, [Os(II)(dpzm)(η 6 -p-cym)Cl]BF4 (dpzm = di(1H-pyrazol-1-yl)methane; η 6 -p-cym = para-cymene), with a formula of C17H22BClF4N4Os (referred to herein as 1) was isolated from the reaction of [(η 6 -p-cym)Os(µ-Cl)(Cl)]2 with dpzm dissolved in acetonitrile and under a flow of nitrogen gas. It was characterized by spectroscopic techniques (viz., FTIR, 1H NMR, UV-Visible absorption). Yellow crystal blocks of 1 were grown by the slow evaporation from the methanolic solution of its powder. The single-crystal X-ray structure of 1 was solved by diffraction analysis on a Bruker APEX Duo CCD area detector diffractometer using the Cu(Kα), λ = 1.54178 Å as the radiation source, and 1 crystallizes in the monoclinic crystal system and the C2/c (no. 15) space group.en_US
dc.language.isoenen_US
dc.publisherMDPIen_US
dc.relation.ispartofseriesmolbank;
dc.subjectarene osmium(II) complexen_US
dc.subjectdi(1H-pyrazol-1-yl)methaneen_US
dc.subjectpara-cymeneen_US
dc.subjectpiano stool geometryen_US
dc.subjectpseudo-octahedral geometryen_US
dc.titleChlorido-(η 6 -p-cymene)-(bis(pyrazol-1-yl)methaneκ 2N,N0 )Osmium(II) Tetrafluoroborate, C17H22BClF4N4Osen_US
dc.typeArticleen_US


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